| Autor: |
Zhong-Lin Zang, Qi Wang, Zhi-Chao Dong, Sheng-Yao Huang, Hao-Zeng Wu, Cheng-He Zhou, Gui-Xin Cai |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Journal of Saudi Chemical Society, Vol 27, Iss 4, Pp 101673- (2023) |
| Druh dokumentu: |
article |
| ISSN: |
1319-6103 |
| DOI: |
10.1016/j.jscs.2023.101673 |
| Popis: |
α,β-Unsaturated ketone is one of the important building blocks of the plenty of alkaloids, spices and pharmaceutical agents. Herein, we describe a peroxide-free electrochemical strategy to realize site-selective allylic C − H oxidation for the synthesis of α,β-unsaturated ketones. This electrochemically driven oxidation exhibits a broad substrate scope. Mechanistic investigations of this reaction uncovered HOAc and H2O as the oxygen source to achieve peroxide-free electrochemical allylic C − H oxidation. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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