Isotypic crystal structures of 2,6-dibromo-N,N-bis(4-nitrophenyl)aniline and 2,6-dichloro-N,N-bis(4-nitrophenyl)aniline
| Autor: | Paul Kautny, Johannes Fröhlich, Berthold Stöger, Matthias Weil |
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| Jazyk: | angličtina |
| Rok vydání: | 2014 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 8, Pp 65-67 (2014) |
| Druh dokumentu: | article |
| ISSN: | 1600-5368 16005368 |
| DOI: | 10.1107/S1600536814010964 |
| Popis: | In the molecules of the two isotypic title compounds, C18H11Br2N3O4 (I) and C18H11Cl2N3O4 (II), the triphenylamine N atoms show no sign of pyramidalization, with marginal displacements of the N atoms from the mean plane of the three connecting C atoms: 0.0058 (13) Å for the Br compound (I) and 0.0074 (9) Å for the Cl compound (II). In the crystals, molecules are linked through C—H...O hydrogen bonds between phenyl rings and nitro groups and by X...O (X = Br, Cl) interactions, that are shorter than the sum of the van der Waals radii, leading to a three-dimensional network. |
| Databáze: | Directory of Open Access Journals |
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