Reaction of potassium germabenzenide with benzil: Unusual ring opening to form a unique polycyclic penta-coordinated germanate

Autor: Tsuji Shingo, Nishino Ryohei, Tokitoh Norihiro, Yamada Hiroko, Mizuhata Yoshiyuki
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Main Group Metal Chemistry, Vol 47, Iss 1, Pp 4588-92 (2024)
Druh dokumentu: article
ISSN: 2191-0219
DOI: 10.1515/mgmc-2023-0031
Popis: The reaction of potassium 2-t-Bu-germabenzenide, in which the anionic carbon atom of phenyl anion is replaced with a germanium atom, with benzil resulted in the 1:2 reaction to give a unique penta-coordinated germanate having a 1,3,2-dioxagermole skeleton. This clearly reflects the characteristics of the germabenzenide as a divalent germanium species.
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