Hexakis(acetonitrile-κN)ruthenium(II) bis(hexabromocarbadodecaborate) acetonitrile solvate

Autor: Anna Larsen, Emil Lobkovsky, Shawn Eady, Jason Diaz, Joshua Masland
Jazyk: angličtina
Rok vydání: 2010
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 66, Iss 3, Pp m325-m326 (2010)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536810006252
Popis: The title compound, [Ru(NCCH3)6](CH6B11Br6)2·CH3CN, consists of the 'naked' ruthenium(II) cation surrounded by six acetonitrile molecules, each coordinated via the nitrogen atoms in a linear or nearly-linear fashion in a typical octahedral over-all arrangement. The cation is balanced by the two hexa-bromocarborane cage anionic fragments [CB11H6Br6]. Weak C—H...Br and B—H...Br interactions link neighboring anions.
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