Hexakis(acetonitrile-κN)ruthenium(II) bis(hexabromocarbadodecaborate) acetonitrile solvate
Autor: | Anna Larsen, Emil Lobkovsky, Shawn Eady, Jason Diaz, Joshua Masland |
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Jazyk: | angličtina |
Rok vydání: | 2010 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E, Vol 66, Iss 3, Pp m325-m326 (2010) |
Druh dokumentu: | article |
ISSN: | 16005368 1600-5368 |
DOI: | 10.1107/S1600536810006252 |
Popis: | The title compound, [Ru(NCCH3)6](CH6B11Br6)2·CH3CN, consists of the 'naked' ruthenium(II) cation surrounded by six acetonitrile molecules, each coordinated via the nitrogen atoms in a linear or nearly-linear fashion in a typical octahedral over-all arrangement. The cation is balanced by the two hexa-bromocarborane cage anionic fragments [CB11H6Br6]. Weak C—H...Br and B—H...Br interactions link neighboring anions. |
Databáze: | Directory of Open Access Journals |
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