| Autor: |
Panagiotis Oikonomopoulos, Varvara Pagkali, Evangelia Kritikou, Anthi Panara, Marios G. Kostakis, Nicolaos S. Thomaidis, Thomais G. Tziotzi, Anastasios Economou, Christos Kokkinos, Giannis S. Papaefstathiou |
| Jazyk: |
angličtina |
| Rok vydání: |
2022 |
| Předmět: |
|
| Zdroj: |
Chemistry, Vol 5, Iss 1, Pp 19-30 (2022) |
| Druh dokumentu: |
article |
| ISSN: |
2624-8549 |
| DOI: |
10.3390/chemistry5010002 |
| Popis: |
In an attempt to expand the coordination chemistry of N,N′-bis(2,4-dicarboxyphenyl)-oxalamide (H6L) ligand, we isolated and structurally characterized two new Fe(II) Metal-Organic Frameworks (MOFs), namely [Fe2(H2L)(H2O)5] (3D-Fe-MOF) and [Fe(H4L)(H2O)2]∙2H2O, (2D-Fe-MOF) by carefully adjusting the reaction conditions to achieve the optimal degree of deprotonation of the bridging ligand. Both MOFs were found stable in water, as evidenced by powder X-ray diffraction data and their ability to sorb glucose (GLU) from either an aqueous solution or artificial sweat was investigated only to show negligible sorption. A graphite paste sensor (GPE) using the 3D-Fe-MOF as a modifier was fabricated. The 3D-Fe-MOF modified GPE was assessed for non-enzymatic GLU detection in aqueous solution at pH 6 via differential pulse voltammetry and the preliminary results were discussed. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
|
|
Nepřihlášeným uživatelům se plný text nezobrazuje |
K zobrazení výsledku je třeba se přihlásit.
|
