Correlation of chemical structures of thiazole accelerators with rheokinetic properties of elastomeric compounds

Autor:	Yu. А. Glebova, А. V. Krylov, V. V. Egorova, V. А. Scherschnev, S. V. Reznichenko, Yu. I. Lyakin
Jazyk:	ruština
Rok vydání:	2014
Předmět:	vulcanization accelerators chemical structures rheokinetic properties sulfur vulcanization activators of vulcanization shungite. Chemistry QD1-999
Zdroj:	Тонкие химические технологии, Vol 9, Iss 5, Pp 55-60 (2014)
Druh dokumentu:	article
ISSN:	2410-6593 2686-7575
Popis:	The quantum-chemical calculation of structures of sulfur vulcanization organic thiazole accelerators was performed. It was established that there is a correlation between the atomic electronegativity of nitrogen, the S–N length bond of and the rheokinetic properties of sulfur vulcanizates with Shungite and ZnO as activators. Moreover, scorching time was influenced on type of an activator. It should be noted that in the presence of Shungite under vulcanization began earlier than with ZnO except for MBT. So the strength of the physical adsorption of MBT on the surface of ZnO similars to Shungite.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/dda1072bf3254f9ebbc20e238abc058d Zobrazit plný text záznamu View record in DOAJ