| Popis: |
The degradation of pollutants in wastewater using abundant resources and renewable energy sources, such as light, is attractive from an environmental perspective. ZnO is a well-known photocatalytic material. Therefore, in this study, a hierarchical ZnO microsphere precursor was prepared using a hydrothermal method. The precursor was subsequently annealed at different temperatures, which enabled the production of a ZnO catalyst having a controllable morphology. Specifically, as the annealing temperature increased, the precursor crystallized into hexagonal wurtzite and the crystallinity also increased. The catalysts were tested for their photocatalytic activity for the degradation of dye molecules (methylene blue and rhodamine B), and the catalyst sample annealed at 400 °C showed the best photocatalytic activity. The origin of this activity was studied using electron paramagnetic resonance spectroscopy and transient photocurrent measurements, and the structure of the optimal catalyst was invested using electron microscopy measurements, which revealed that it was formed of two-dimensional nanosheets having smooth surfaces, forming a 2D cellular network. Thus, we have presented a promising photocatalyst for the mineralization of organic contaminants in wastewater. |
