Crystal structure of bis{S-octyl-3-[(thiophen-2-yl)methylidene]dithiocarbazato-κ2N3,S}nickel(II)
Autor: | Sultana Shakila Khan, Md. Belayet Hossain Howlader, Md. Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando |
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Jazyk: | angličtina |
Rok vydání: | 2023 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 79, Iss 8, Pp 714-717 (2023) |
Druh dokumentu: | article |
ISSN: | 2056-9890 20569890 |
DOI: | 10.1107/S2056989023005935 |
Popis: | In the title complex, [Ni(C14H21N2S3)2], the nickel(II) atom is located on a crystallographic inversion center and exhibits a square-planar coordination environment, being coordinated by two negatively charged N,S-chelating ligands in a trans configuration. In the crystal, the non-H atoms of the complex are practically coplanar (r.m.s. deviation of fitted atoms = 0.135 Å), and the angle between the thienyl and the chelating rings is 6.7 (1)°. The molecules stack at a distance of 3.623 (2) Å along the b-axis direction. |
Databáze: | Directory of Open Access Journals |
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