Effect of the Carbon Support and Conditions on the Carbothermal Synthesis of Cu-Molybdenum Carbide and Its Application on CO2 Hydrogenation to Methanol

Autor:	Ana Belén Dongil, Elodie Blanco, Juan José Villora-Picó, Antonio Sepúlveda-Escribano, Inmaculada Rodríguez-Ramos
Jazyk:	angličtina
Rok vydání:	2022
Předmět:	CO2 hydrogenation molybdenum carbide copper methanol carbon Chemistry QD1-999
Zdroj:	Nanomaterials, Vol 12, Iss 7, p 1048 (2022)
Druh dokumentu:	article
ISSN:	12071048 2079-4991
DOI:	10.3390/nano12071048
Popis:	The synthesis of methanol by carbon dioxide hydrogenation has been studied using copper-molybdenum carbides supported on high surface area graphite, reduced graphene oxide and carbon nanotubes. The synthesis conditions and the effect of the support were studied. The catalysts were prepared in situ using H2 or He at 600 °C or 700 °C. Both molybdenum carbide and oxycarbide were obtained. A support with less reactive carbon resulted in lower proportion of carbide obtained. The best results were achieved over a 5 wt.% Cu and 10 wt.% Mo on high surface area graphite that reached 96.3% selectivity to methanol.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/0fc2a7b8ca8c41babee712ffa4a53845 Zobrazit plný text záznamu View record in DOAJ