[MII(NCS)2(nia)2(OH2)]: Preparation, Crystal Structure and Thermal Properties (MII = Mn, Fe; nia = nicotinamide)
| Autor: | Marta Počkaj, Nives Kitanovski, Boris Čeh, Romana Cerc-Korošec |
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| Jazyk: | angličtina |
| Rok vydání: | 2017 |
| Předmět: | |
| Zdroj: | Acta Chimica Slovenica, Vol 64, Iss 2, Pp 342-348 (2017) |
| Druh dokumentu: | article |
| ISSN: | 1318-0207 1580-3155 |
| DOI: | 10.17344/acsi.2017.3192 |
| Popis: | Two novel isostructural coordination compounds of manganese(II) (1) and iron(II) (2) with common formula [MII(NCS)2(nia)2(OH2)2] have been prepared from water solution of appropriate metal salt, nicotinamide and KSCN. Their crystal structures were determined by means of X-ray diffraction on single crystals. The mononuclear title compounds crystallize in a triclinic P–1 space group with six monodentate octahedrally arranged ligands around the metal centre. The coordination molecules are self-assembled with an extended network of hydrogen bonds into a three-dimensional structure. Additionally, 1 and 2 were characterized with infrared spectroscopy, magnetic measurements and thermal analysis. |
| Databáze: | Directory of Open Access Journals |
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