| Autor: |
Shu-Yu Chen, Sheng-Heng Chung |
| Jazyk: |
angličtina |
| Rok vydání: |
2021 |
| Předmět: |
|
| Zdroj: |
Nanomaterials, Vol 11, Iss 8, p 2083 (2021) |
| Druh dokumentu: |
article |
| ISSN: |
2079-4991 |
| DOI: |
10.3390/nano11082083 |
| Popis: |
An inexpensive sulfur cathode with the highest possible charge storage capacity is attractive for the design of lithium-ion batteries with a high energy density and low cost. To promote existing lithium–sulfur battery technologies in the current energy storage market, it is critical to increase the electrochemical stability of the conversion-type sulfur cathode. Here, we present the adoption of a carbon nanofoam as an advanced current collector for the lithium–sulfur battery cathode. The carbon nanofoam has a conductive and tortuous network, which improves the conductivity of the sulfur cathode and reduces the loss of active material. The carbon nanofoam cathode thus enables the development of a high-loading sulfur cathode (4.8 mg cm−2) with a high discharge capacity that approaches 500 mA·h g−1 at the C/10 rate and an excellent cycle stability that achieves 90% capacity retention over 100 cycles. After adopting such an optimal cathode configuration, we superficially coat the carbon nanofoam with graphene and molybdenum disulfide (MoS2) to amplify the fast charge transfer and strong polysulfide-trapping capabilities, respectively. The highest charge storage capacity realized by the graphene-coated carbon nanofoam is 672 mA·h g−1 at the C/10 rate. The MoS2-coated carbon nanofoam features high electrochemical utilization attaining the high discharge capacity of 633 mA·h g−1 at the C/10 rate and stable cyclability featuring a capacity retention approaching 90%. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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