| Autor: |
Esha Mishra, WaiKiat Chin, Kayleigh A McElveen, Thilini K Ekanayaka, M Zaid Zaz, Gauthami Viswan, Ruthi Zielinski, Alpha T N’Diaye, David Shapiro, Rebecca Y Lai, Robert Streubel, Peter A Dowben |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
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| Zdroj: |
JPhys Materials, Vol 7, Iss 1, p 015010 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2515-7639 |
| DOI: |
10.1088/2515-7639/ad1b35 |
| Popis: |
Adding Fe _3 O _4 nanoparticles to composites of [Fe(Htrz) _2 (trz)](BF _4 ) spin-crossover polymer and polyaniline (PANI) drives a phase separation of both and restores the molecular structure and cooperative effects of the spin-crossover polymer without compromising the increased conductivity gained through the addition of PANI. We observe an increased on-off ratio for the DC conductivity owing to an enlarged off state resistivity and a 20 times larger AC conductivity of the on state compared with DC values. The Fe _3 O _4 nanoparticles, primarily confined to the [Fe(Htrz) _2 (trz)](BF _4 ) phase, are ferromagnetically coupled to the local moment of the spin-crossover molecule suggesting the existence of an exchange interaction between both components. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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