Enhancing photocatalytic efficiency of type II V2O5/TiO2 heterojunctions for malachite green dye using solar simulator irradiation

Autor: M. Zahid Shafiq, Wajeehah Shahid, Samiah Shahid, M.I. Khan, Jeong Ryeol Choi, Eman A. Al-Abbad
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Saudi Chemical Society, Vol 28, Iss 3, Pp 101869- (2024)
Druh dokumentu: article
ISSN: 1319-6103
DOI: 10.1016/j.jscs.2024.101869
Popis: Photocatalytic responses and synergistic effects of V2O5, TiO2, and V2O5/TiO2 heterostructures with varied ratios have been investigated, revealing promising outcomes. The successful synthesis of nanostructures and heterostructures was verified through energy-dispersive X-ray spectroscopy, X-ray diffraction, and Fourier transform infrared spectroscopy analyses. Notably, ultraviolet–visible spectroscopy and photoluminescence spectral studies confirmed that the optical band gap of V2O5/TiO2 heterostructures increases with higher TiO2 concentrations. These findings enhance our understanding of the agglomerated heterostructures of V2O5/TiO2, particularly with ratios of 1:1 and 1:3, showcasing potential applications in photocatalysis. Furthermore, their performance was subjected to Malachite Green dye degradation using a solar simulator, achieving an impressive efficiency of 93.29%. Additionally, the photocatalytic efficacy was assessed through reusability experiments over three cycles. Remarkably, the heterostructures exhibited stability across these cycles, suggesting their potential for extended use in diverse photocatalytic purposes. The importance of these results is the applicability of our fabricated V2O5/TiO2 heterostructures as a photocatalyst with high performance, especially in the realm of sustainable and efficient dye degradation processes.
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