Optimization of graphene nanoplatelets dispersion and nano-filler loading in bio-based polymer nanocomposites based on tensile and thermogravimetry analysis

Autor: Dalila Shahdan, Ruey Shan Chen, Sahrim Ahmad
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 15, Iss , Pp 1284-1299 (2021)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2021.08.130
Popis: The incorporation of graphene nanoplatelets (GNPs) has attracted massive attention in polymer nanocomposite production. In this work, GNPs reinforced nanocomposites of liquid natural rubber (LNR) toughened poly (lactic acid) (PLA)/poly (aniline) (PANi) were fabricated through melt-mixing using internal mixer. The effects of ultrasonic treatment period, mixing rotor speed and GNPs loadings in PLA-LNR/PANi was investigated. A premix ultrasonication of LNR/PANi with GNPs for 1 h was found to be the most effective period as compared to the longer sonication time. The best melt-mixing of the materials was achieved at 100 rpm, in accordance to the tensile properties as well as homogeneous dispersion and distribution of nano-filler as shown in thermogravimetry analysis. Results revealed that the optimum loading was found at 0.4 wt.% of GNPs with excellent enhancement in tensile strength (25 MPa), tensile modulus (1188.9 MPa) and thermal stability of the nanocomposite, as proven by ANOVA statistical analysis.
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