| Autor: |
Malay Dolai, Urmila Saha |
| Jazyk: |
angličtina |
| Rok vydání: |
2020 |
| Předmět: |
|
| Zdroj: |
Heliyon, Vol 6, Iss 10, Pp e04942- (2020) |
| Druh dokumentu: |
article |
| ISSN: |
2405-8440 |
| DOI: |
10.1016/j.heliyon.2020.e04942 |
| Popis: |
A copper (II) complex [Cu(4-MeO-salox)2](1) based on saloxime ligand was synthesized and characterized using single crystal X-ray diffraction studies. The geometry was further emphasized by DFT optimization. The complex was found to be pseudo-macrocyclic mononuclear having square planer geometry. The complex 1 shows two types of supramolecular hydrogen bonding interactions and forms the multi-dimensional framework with the help of CH∙∙∙O, OH∙∙∙O and π∙∙∙π(chelate) interactions. The complex 1 performs as efficient catalyst in catecholase activiy having good turnover number (TON), kcat = 22.97 h−1 where TON is the number of catechol molecules converted into quinone by catalyst molecule i.e 1 in a unit time. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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