Nickel–Iron-Layered Double Hydroxide Electrocatalyst with Nanosheets Array for High Performance of Water Splitting

Autor: Zhi Lu, Shilin Li, Laiyuan Ning, Kun Tang, Yifan Guo, Long You, Chong Chen, Guangxin Wang
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Molecules, Vol 29, Iss 9, p 2092 (2024)
Druh dokumentu: article
ISSN: 1420-3049
DOI: 10.3390/molecules29092092
Popis: Developing high-performance and cost-competitive electrocatalysts have great significance for the massive commercial production of water-splitting hydrogen. Ni-based electrocatalysts display tremendous potential for electrocatalytic water splitting. Herein, we synthesize a novel NiFe-layered double hydroxide (LDH) electrocatalyst in nanosheets array on high-purity Ni foam. By adjusting the Ni/Fe ratio, the microstructure, and even the behavior of the electrocatalyst in the oxygen evolution reaction (OER), changes significantly. The as-obtained material shows a small overpotential of 223 mV at 10 mAcm−2 as well as a low Tafel slope of 48.9 mV·dec−1 in the 1 M KOH electrolyte. In addition, it can deliver good stability for at least 24 h of continuous working at 10 mAcm−2. This work proposes a strategy for engineering catalysts and provides a method for the development of other Ni-based catalysts with excellent performance.
Databáze: Directory of Open Access Journals
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