Influence of phthalocyanine nanowire dye on the performance of titanium dioxide-metal organic framework nanocomposite for dye-sensitized solar cells

Autor: Phuti S Ramaripa, Kwena D. Modibane, Katlego Makgopa, Ostar A Seerane, Manoko S Maubane-Nkadimeng, Edwin Makhado, Sadanand Pandey
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Chemical Engineering Journal Advances, Vol 14, Iss , Pp 100485- (2023)
Druh dokumentu: article
ISSN: 2666-8211
DOI: 10.1016/j.ceja.2023.100485
Popis: In clean energy, dye-sensitized solar cells (DSSCs) have become a key tool for the photovoltaic effect. Copper phthalocyanine nanowire (CuPcNW) dyes can be used in DSSCs to generate low-cost devices, light-harvesting, fast electron transfer materials, and prevent recombination processes, as well as improve conductivity. This study investigates the effect of CuPcNW dye on TiO2, MOF, and TiO2-MOF in photovoltaic performance. Electrochemical characterizations such as cyclic voltammetry and electrochemical impedance spectroscopy (EIS) have also revealed the half-wave peak potentials of the ternary nanocomposite with values of 0.44 and 0.35 V for the oxidation and reduction reversible reactions. The EIS behavior revealed the improved conductivity of the nanocomposite with a value of 244 µS/cm. It was seen that the TiO2-MOF/CuPcNW nanocomposite achieved a maximum power conversion efficiency of 6.467 % owing to the presence of CuPcNW, which improved the photocurrent density, faster electron transport, and reduced charge recombination in the nanocomposite.
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