Bis[2-(2-pyridylmethyleneamino)benzenesulfonato-κ3N,N′,O]cadmium(II) dihydrate
| Autor: | Miao Ou-Yang, Xue-Ren Huang, Yun-Liang Zhang, Yi-Min Jiang |
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| Jazyk: | angličtina |
| Rok vydání: | 2008 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 64, Iss 11, Pp m1461-m1461 (2008) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536808034387 |
| Popis: | The title complex, [Cd(Paba)2]·2H2O or [Cd(C12H9N2O3S)2]·2H2O, was synthesized by the reaction of the potassium salt of 2-(2-pyridylmethyleneamino)benzenesulfonic acid (PabaK) with CdCl2·2.5H2O in methanol. The CdII atom lies on a crystallographic twofold axis and is coordinated by four N atoms and two O atoms from two deprotonated tridentate 2-(2-pyridylmethyleneamino)benzenesulfonate ligands in a slightly distorted octahedral environment. There are extensive hydrogen bonds of the type O—H...O between the uncoordinated water molecules and the sulfonate O atoms, through which the complex forms a layered structure parallel to (001). |
| Databáze: | Directory of Open Access Journals |
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