Generation of non-stabilized alkyl radicals from thianthrenium salts for C–B and C–C bond formation

Autor: Cheng Chen, Zheng-Jun Wang, Hongjian Lu, Yue Zhao, Zhuangzhi Shi
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: Nature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
Druh dokumentu: article
ISSN: 2041-1723
DOI: 10.1038/s41467-021-24716-2
Popis: The generation of non-stabilized alkyl radicals from sulfonium salts has been a challenge for several decades. Here, the authors show the treatment of S-(alkyl) thianthrenium salts, which can generate non-stabilized alkyl radicals as key intermediates that enable controlled and selective reactions under mild photoredox conditions.
Databáze: Directory of Open Access Journals