| Autor: |
Ekaterina Zorina-Tikhonova, Anna Matyukhina, Ivan Skabitskiy, Maksim Shmelev, Denis Korchagin, Konstantin Babeshkin, Nikolay Efimov, Mikhail Kiskin, Igor Eremenko |
| Jazyk: |
angličtina |
| Rok vydání: |
2020 |
| Předmět: |
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| Zdroj: |
Crystals, Vol 10, Iss 12, p 1130 (2020) |
| Druh dokumentu: |
article |
| ISSN: |
2073-4352 |
| DOI: |
10.3390/cryst10121130 |
| Popis: |
The reaction of (NBu4)2Bzmal (where Bzmal2− is benzylmalonate dianion) with Co(OAc)2∙4H2O gives the [Co(Bzmal)(EtOH)(H2O)]n 2D-polymer (1). The addition of 2,2′-bipyridine (bpy) to the starting system results in the [Co(Bzmal)(bpy)2]·H2O·EtOH molecular complex (2). Their molecular and crystal structures were analyzed by single-crystal X-ray crystallography. An analysis of the static magnetic data supported by the SA-CASSCF/NEVPT2 calculations revealed the presence of easy-plane magnetic anisotropy in both complexes. The AC susceptibility data confirm that both complexes show a slow field-induced (HDC = 1000 Oe) magnetic relaxation behavior. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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