Environmental Impact of Polyurethane-Based Aerogel Production: Influence of Solvents and Solids Content

Autor: Seyed Ahmad Aldaghi, Mattia Costamagna, Massimo Perucca, Esther Pinilla-Peñalver, Darío Cantero, Amaya Romero, Luz Sánchez-Silva
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Resources, Vol 13, Iss 10, p 138 (2024)
Druh dokumentu: article
ISSN: 2079-9276
DOI: 10.3390/resources13100138
Popis: This study provides a comprehensive analysis of the environmental impacts associated with the synthesis of polyurethane (PUR) aerogels. The synthesis process incorporates various solvents and solids contents into the formulation, with the primary objective of enhancing the physical properties of the aerogels for broad industrial applications. Nine experimental scenarios were explored, grouped into two sets based on the variables studied. A detailed Life Cycle Assessment (LCA) was conducted to evaluate the environmental impacts of all formulated PUR aerogels. The findings indicate that a solvent solution of 100% ethyl acetate (EtOAc) results in lower environmental impacts compared to other tested formulations. Notably, a solvent solution comprising 75% acetonitrile (ACN) and 25% EtOAc exhibited the highest environmental Key Performance Indicator (εKPI) among the tested material formulations, closely followed by the PUR aerogel obtained using acetone as a solvent. Furthermore, this study underscores the necessity of performing an integrated LCA that considers both environmental and functional aspects. While reducing the solids content is environmentally advantageous, it may present challenges in terms of material functionality. This is illustrated by the PUR aerogel synthesized with the lowest solids content of 3.2 wt.%, which demonstrated high deformability, thereby complicating the determination of a reliable Young’s modulus for analysis.
Databáze: Directory of Open Access Journals