Optical cycling of AlF molecules

Autor: S Hofsäss, M Doppelbauer, S C Wright, S Kray, B G Sartakov, J Pérez-Ríos, G Meijer, S Truppe
Jazyk: angličtina
Rok vydání: 2021
Předmět:
Zdroj: New Journal of Physics, Vol 23, Iss 7, p 075001 (2021)
Druh dokumentu: article
ISSN: 1367-2630
DOI: 10.1088/1367-2630/ac06e5
Popis: Aluminium monofluoride (AlF) is a promising candidate for laser cooling and trapping at high densities. We show efficient production of AlF in a bright, pulsed cryogenic buffer gas beam, and demonstrate rapid optical cycling on the Q rotational lines of the A ^1 Π ↔ X ^1 Σ ^+ transition. We measure the brightness of the molecular beam to be >10 ^12 molecules per steradian per pulse in a single rotational state and present a new method to determine its velocity distribution in a single shot. The photon scattering rate of the optical cycling scheme is measured using three different methods, and is compared to theoretical predictions of the optical Bloch equations and a simplified rate equation model. Despite the large number of Zeeman sublevels (up to 216 for the Q(4) transition) involved, a high scattering rate of at least 17(2) × 10 ^6 s ^−1 can be sustained using a single, fixed-frequency laser without the need to modulate the polarisation. We deflect the molecu-lar beam using the radiation pressure force and measure an acceleration of 8.7(1.5) × 10 ^5 m s ^−2 . Losses from the optical cycle due to vibrational branching to X ^1 Σ ^+ , v ″ = 1 are addressed efficiently with a single repump laser. Further, we investigate two other loss channels, parity mixing by stray electric fields and photo-ionisation. The upper bounds for these effects are sufficiently low to allow loading into a magneto‐optical trap.
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