| Autor: |
Akinobu Naka, Maho Inoue, Haruna Kawabe, Hisayoshi Kobayashi |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
AppliedChem, Vol 4, Iss 1, Pp 29-41 (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2673-9623 |
| DOI: |
10.3390/appliedchem4010003 |
| Popis: |
Rhodium-catalyzed reactions of 3-ethynyl-2-pentamethyldisilanylthiophene derivatives (1a–1c) have been reported. At 110 °C, compounds 1a–1c reacted in the presence of a rhodium complex catalyst, yielding thiophene-fused siloles (2a–2c) through intramolecular trans-bis-silylation. To understand the production of 2a from 1a, the mechanism was investigated using density functional theory (DFT) calculations. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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