Anticorrosion action of the olive leaf compounds extracted under optimal parameters as determined with experimental design

Autor: Touazi Souad, Bučko Mihael M., Maizia Radouane, Sahi Samira, Zaidi Nadia, Makhloufi Laid
Jazyk: angličtina
Rok vydání: 2023
Předmět:
Zdroj: Journal of the Serbian Chemical Society, Vol 88, Iss 2, Pp 169-182 (2023)
Druh dokumentu: article
ISSN: 0352-5139
1820-7421
DOI: 10.2298/JSC220513064T
Popis: In this study, an agricultural waste product was used to prepare a green corrosion inhibitor based on olive leaves (Olea europaea var. syslvestris). Firstly, an optimization study of antioxidant activity of O. europaea leaves monitored by the DPPH free radical trapping method, was carried out using full factorial design. In the second step, the extract obtained under optimal conditions was tested as a green corrosion inhibitor for steel in 0.5 mol dm-3 HCl, using gravimetric and electrochemical methods. The results obtained by various techniques showed that the extract acted as a mixed-type inhibitor. The adsorption of the inhibitor was spontaneous (ΔGads = −12.443 kJ mol-1), through the mechanism of physical adsorption, and it obeyed the Langmuir adsorption isotherm. The highest corrosion inhibition efficiency of 92 % was obtained for 2.8 10-3 g cm-3of inhibitor, as measured by gravimetric method.
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