Influence of carbon on microstructure and mechanical properties of magnetron sputtered TaW coatings

Autor: S. Fritze, M. Hans, L. Riekehr, B. Osinger, E. Lewin, J.M. Schneider, U. Jansson
Jazyk: angličtina
Rok vydání: 2020
Předmět:
Zdroj: Materials & Design, Vol 196, Iss , Pp 109070- (2020)
Druh dokumentu: article
ISSN: 0264-1275
89154800
DOI: 10.1016/j.matdes.2020.109070
Popis: (Ta,W) and (Ta,W):C films with ~5 at.% C were deposited by non-reactive magnetron sputtering. They crystallised in a bcc structure with a columnar microstructure. The solid solubility of C in (Ta,W) alloys is very low, which suggests that the (Ta,W):C films are supersaturated with respect to carbon. This was confirmed by diffraction and atom probe tomography (APT) showing that carbon is in the as-deposited (Ta,W):C films homogeneously distributed in the structure without carbide formation or carbon segregation. Annealing at 900 °C for 2 h showed no significant column coarsening but an increased defect density at the column boundaries in the (Ta,W):C films. The films were still supersaturated with respect to carbon but APT showed a partial segregation of carbon presumably to defect-rich column boundaries after annealing. The (Ta,W) films exhibited a hardness of ~12–13 GPa. Alloying with carbon increased the hardness to ~17 GPa. The hardness increased to ~19 GPa for the annealed (Ta,W):C films. This annealing-induced hardness increase was explained by C segregation to the more defect-rich column boundaries, which restricts dislocation movements. (Ta,W):C coatings may be a potential alternative to ceramic coatings, worth exploring further by small scale mechanical testing to investigate if these materials are ductile.
Databáze: Directory of Open Access Journals
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