Synthesis of Au microwires by selective oxidation of Au–W thin-film composition spreads

Autor: Sven Hamann, Hayo Brunken, Steffen Salomon, Robert Meyer, Alan Savan and Alfred Ludwig
Jazyk: angličtina
Rok vydání: 2013
Předmět:
Zdroj: Science and Technology of Advanced Materials, Vol 14, Iss 1, p 015003 (2013)
Druh dokumentu: article
ISSN: 1468-6996
1878-5514
DOI: 10.1088/1468-6996/14/1/015003
Popis: We report on the stress-induced growth of Au microwires out of a surrounding Au–W matrix by selective oxidation, in view of a possible application as 'micro-Velcro'. The Au wires are extruded due to the high compressive stress in the tungsten oxide formed by oxidation of elemental W. The samples were fabricated as a thin-film materials library using combinatorial sputter deposition followed by thermal oxidation. Sizes and shapes of the Au microwires were investigated as a function of the W to Au ratio. The coherence length and stress state of the Au microwires were related to their shape and plastic deformation. Depending on the composition of the Au–W precursor, the oxidized samples showed regions with differently shaped Au microwires. The Au48W52 composition yielded wires with the maximum length to diameter ratio due to the high compressive stress in the tungsten oxide matrix. The values of wire length (35 μm) and diameter (2 μm) achieved at the Au48W52 composition are suitable for micro-Velcro applications.
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