Crystal structure and Hirshfeld surface analysis of poly[[di-μ3-glycine-lithium] perchlorate]
| Autor: | Palanisamy Revathi, Janani S. Mohan, Thangavelu Balakrishnan, Kandasamy Ramamurthi, Subbiah Thamotharan |
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| Jazyk: | angličtina |
| Rok vydání: | 2019 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 75, Iss 2, Pp 134-138 (2019) |
| Druh dokumentu: | article |
| ISSN: | 2056-9890 20569890 |
| DOI: | 10.1107/S2056989018018145 |
| Popis: | In the title salt, {[Li(C2H5NO2)2]ClO4}n, the Li+ cation is coordinated by four carboxylate oxygen atoms of the glycine molecules with a distorted tetrahedral geometry. The glycine exists in a zwitterionic form with protonated amino and deprotonated carboxylate groups. In the crystalline state, the title salt is primarily stabilized by intermolecular N—H...O and Cα—H...O interactions which interconnect various units. Hirshfeld surface analysis indicates that the intermolecular H...O/O...H interactions are the most important contributors to the crystal packing. |
| Databáze: | Directory of Open Access Journals |
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