Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis(dimethyl sulfoxide)nickel(II)

Autor: Amel Djedouani, Sihem Boufas, Abderrahmen Bendaas, Magali Allain, Gilles Bouet
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 10, Pp m1205-m1206 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809034655
Popis: In the title compound, [Ni(C8H7O4)2{(CH3)2SO}2], the NiII atom is located on a crystallographic centre of symmetry and has a distorted octahedral coordination geometry of type MO6. The bidentate dehydroacetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O atoms in the axial positions.
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