Autor: |
Masahiro Kako, Masato Kai, Masanori Yasui, Michio Yamada, Yutaka Maeda, Takeshi Akasaka |
Jazyk: |
angličtina |
Rok vydání: |
2024 |
Předmět: |
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Zdroj: |
Beilstein Journal of Organic Chemistry, Vol 20, Iss 1, Pp 1179-1188 (2024) |
Druh dokumentu: |
article |
ISSN: |
1860-5397 |
DOI: |
10.3762/bjoc.20.100 |
Popis: |
The addition reaction of C60 with silylene 1, a silicon analog of carbene, yielded the corresponding bis-adduct 3. The structure of 3 was determined by single-crystal X-ray structure analysis, representing the first example of a crystal structure of a silirane (silacyclopropane) derivative of fullerenes. Electrochemical measurements confirmed that the redox potentials of 3 are shifted cathodically compared to those of the parent mono-adduct 2. Density functional theory (DFT) calculations provided the basis for the electronic properties of compound 3. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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