(Nitrito-κ2O,O′)bis[tris(4-methylphenyl)phosphane-κP]silver(I)

Autor: Frederick P. Malan, Kariska Potgieter, Reinout Meijboom
Jazyk: angličtina
Rok vydání: 2022
Předmět:
Zdroj: IUCrData, Vol 7, Iss 12, p x221148 (2022)
Druh dokumentu: article
ISSN: 2414-3146
24143146
DOI: 10.1107/S2414314622011488
Popis: The molecular structure of the title compound, [Ag(NO2)(C21H21P)2], exhibits a pseudo-tetrahedral coordination around the central AgI atom. The compound crystallizes with one molecule in the asymmetric unit in the monoclinic space group P21/n with a rather long b axis [33.8752 (2) Å]. Weak C—H...O and C—H...N interactions consolidate the crystal packing. The nitrite-O atoms each occupy a single position in the coordination geometry.
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