| Popis: |
Calcined clay and limestone powder composites offer a viable solution for reducing carbon emissions in building materials by allowing significant cement replacement. However, there is a need for further investigation into their impact on durability, especially for low-grade clays. In this study, different ratios of metakaolin and quartz powder are utilized to simulate various grades of calcined clay, while limestone powder is incorporated as a partial cement substitute. Initially, the influence of metakaolin content on rapid chloride migration was analyzed. Subsequently, various analytical techniques such as free water content, Mercury Intrusion Porosimetry (MIP), X-ray diffraction (XRD)/Rietveld method, and electrochemical impedance spectroscopy (EIS) test were employed to investigate the effects of metakaolin contents on the pore structure, phase assemblage, and electrochemical parameters of the blended cementitious system. The relationship between chloride migration coefficient and free water content, critical pore size, and impedance parameters was established to determine the key indicators for chloride migration. The study revealed that systems with partial metakaolin content demonstrate improved chloride resistance in the blended system, which could be predicted using Rct1 from the EIS test. Furthermore, the inclusion of metakaolin and limestone powder facilitated the formation of Monocarboaluminate (Mc) and Hemicarboaluminate (Hc), leading to the refinement of the pore structure and inhibition of chloride transport within the blended material. This study indicates the potential of low-grade calcined clay to enhance the overall durability of the blended cementitious system while contributing to carbon emissions reduction. |
