Sorption-Desorption Behavior of Imazethapyr and Imazapic on Six Brazilian Soils

Autor: M.I.C. MARINHO, W.M. SOUZA, M.F. CABRAL, M.D. CASTRO NETO, M.E.L.R. QUEIROZ, A.A. SILVA
Jazyk: English<br />Spanish; Castilian<br />Portuguese
Rok vydání: 2018
Předmět:
Zdroj: Planta Daninha, Vol 36 (2018)
Druh dokumentu: article
ISSN: 0100-8358
DOI: 10.1590/s0100-83582018360100140
Popis: ABSTRACT: The characterization of sorption-desorption for imazethapyr and imazapic in six agricultural soils was performed to assess the availability of these herbicides in pollution processes. In this pursuit, the batch equilibrium method and high-performance liquid chromatography were used. The magnitude of Kf values ranging from 0.38 to 2.52 mg1-n kg-1 Ln for imazethapyr and 0.43 to 2.72 mg1-n kg-1 Ln for imazapic indicate weak sorption in the evaluated soils. Soil pH (5.1 to 6.1) and iron oxalate affect sorption-desorption of both herbicides but the type and percentage of clay can be the main factor affecting these two processes. A high desorption percentage (>70%) was found in Regosol, Dystric Plinthosol, Ferralsol (for both herbicides), and Dystric Gleysol (only imazapic) soils, which implies in leaching risks of these imidazolinone herbicides into groundwater. Lower desorption (
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