| Autor: |
Yuki Izumida |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
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| Zdroj: |
Journal of Physics Communications, Vol 7, Iss 12, p 125002 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
2399-6528 |
| DOI: |
10.1088/2399-6528/ad1597 |
| Popis: |
The characterization of finite-time thermodynamic processes is of crucial importance for extending equilibrium thermodynamics to nonequilibrium thermodynamics. The central issue is to quantify responses of thermodynamic variables and irreversible dissipation associated with non-quasistatic changes of thermodynamic forces applied to the system. In this study, we derive a simple formula that incorporates the non-quasistatic response coefficients with Onsager’s kinetic coefficients, where the Onsager coefficients characterize the relaxation dynamics of fluctuation of extensive thermodynamic variables of semi-macroscopic systems. Moreover, the thermodynamic length and the dissipated availability that quantifies the efficiency of irreversible thermodynamic processes are formulated in terms of the derived non-quasistatic response coefficients. The present results are demonstrated by using an ideal gas model. The present results are, in principle, verifiable through experiments and are thus expected to provide a guiding principle for the nonequilibrium control of macroscopic thermodynamic systems. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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