Bis(2-{[(9H-fluoren-2-yl)methylidene]amino}phenolato-κ2N,O)zinc methanol disolvate
| Autor: | Young-Inn Kim, Sung-Jae Yun, Inn-Hye Hwang, Dae-Young Kim, Sung Kwon Kang |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 4, Pp m504-m505 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S160053681201272X |
| Popis: | In the title compound, [Zn(C20H14NO)2]·2CH3OH, the ZnII atom lies on a crystallographic twofold rotation axis and is coordinated by two O atoms and two N atoms from two bidentate 2-{[(9H-fluoren-2-yl)methylidene]amino}phenolate ligands within a distorted tetrahedral geometry. The dihedral angle between the two chelate rings is 82.92 (5)°. In the coordinated ligand, the phenol ring is twisted at 30.22 (9)° from the mean plane of the fluorene ring. In the crystal, O—H...O hydrogen bonds link the complex molecules to the methanol solvent molecules. |
| Databáze: | Directory of Open Access Journals |
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