| Autor: |
Ćirin Dejan M., Poša Mihalj M., Krstonošić Veljko S., Milanović Maja Lj. |
| Jazyk: |
English<br />Serbian |
| Rok vydání: |
2012 |
| Předmět: |
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| Zdroj: |
Hemijska Industrija, Vol 66, Iss 1, Pp 21-28 (2012) |
| Druh dokumentu: |
article |
| ISSN: |
0367-598X |
| DOI: |
10.2298/HEMIND110612059C |
| Popis: |
The present study is concerned with the determination of the critical micelle concentration (cmc) of mixed micelles of sodium dodecyl sulfate with one of five nonionic surfactants (Triton X-100, Tween 20, Tween 60, Tween 80 or Tween 85) from conductance measurements. Based on the calculated values of the β parameters we have noticed that SDS-nonionic surfactants mostly showed strong synergistic effect. It was found that nonionic surfactants with mainly longer and more hydrophobic tail show stronger interactions with hydrophobic part of SDS, thus expressing stronger synergism. In SDS-Tween 80 binary system the strongest synergistic effect was noticed. SDS-Tween 85 micellar system showed antagonistic effect, most probably because the presence of the double bond in its three hydrophobic tails (three C18 tails) makes it sterically rigid. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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