Crystal structure of trans-1,4-bis[(trimethylsilyl)oxy]cyclohexa-2,5-diene-1,4-dicarbonitrile

Autor: Florian Glöcklhofer, Johannes Fröhlich, Berthold Stöger, Matthias Weil
Jazyk: angličtina
Rok vydání: 2014
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 70, Iss 8, Pp 77-79 (2014)
Druh dokumentu: article
ISSN: 1600-5368
16005368
DOI: 10.1107/S1600536814014251
Popis: The asymmetric unit of the title compound, C14H22N2O2Si2, contains one half of the molecule, which is completed by inversion symmetry. The cyclohexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs of single bonds [1.5121 (13) and 1.5073 (14) Å]. The tetrahedral angle between the sp3-C atom and the two neighbouring sp2-C atoms in the cyclohexa-2,5-diene ring is enlarged by about 3°.
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