Crystal structure of trans-1,4-bis[(trimethylsilyl)oxy]cyclohexa-2,5-diene-1,4-dicarbonitrile
Autor: | Florian Glöcklhofer, Johannes Fröhlich, Berthold Stöger, Matthias Weil |
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Jazyk: | angličtina |
Rok vydání: | 2014 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E, Vol 70, Iss 8, Pp 77-79 (2014) |
Druh dokumentu: | article |
ISSN: | 1600-5368 16005368 |
DOI: | 10.1107/S1600536814014251 |
Popis: | The asymmetric unit of the title compound, C14H22N2O2Si2, contains one half of the molecule, which is completed by inversion symmetry. The cyclohexa-2,5-diene ring is exactly planar and reflects the bond-length distribution of a pair of located double bonds [1.3224 (14) Å] and two pairs of single bonds [1.5121 (13) and 1.5073 (14) Å]. The tetrahedral angle between the sp3-C atom and the two neighbouring sp2-C atoms in the cyclohexa-2,5-diene ring is enlarged by about 3°. |
Databáze: | Directory of Open Access Journals |
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