Lanthanide Coordination Compounds with Monodentate Coordinated Β-diketone Heteroanalogue - (2,2,2-trichloro-n-(Dipiperidin-1-yl-phosphoryl)acetamide: Synthesis and Spectral Investigations
Autor: | Olena Litsis, Vladimir Ovchynnikov, Tatiana Sliva, Svitlana Shishkina, Vladimir Amirkhanov |
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Jazyk: | angličtina |
Rok vydání: | 2018 |
Předmět: | |
Zdroj: | Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 13, Iss 1, Pp 15-23 (2018) |
Druh dokumentu: | article |
ISSN: | 1857-1727 2345-1688 |
DOI: | 10.19261/cjm.2017.466 |
Popis: | New mononuclear six-coordinate lanthanide coordination compounds [Ln (HL)3Cl3] (HL = (2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamideCCl3C(O)N(H)P(O)[N(CH2)5]2, carbacylamidophosphate (CAPh) type ligand) have been synthesized from non-aqueous solutions. The complexes have been characterized by elemental analysis, spectroscopic methods (FTIR, 1H- and 31P-NMR, UV-Vis). The structure of [Sm(HL)3Cl3] has been further confirmed by single crystal X-ray diffraction analysis. |
Databáze: | Directory of Open Access Journals |
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