Lanthanide Coordination Compounds with Monodentate Coordinated Β-diketone Heteroanalogue - (2,2,2-trichloro-n-(Dipiperidin-1-yl-phosphoryl)acetamide: Synthesis and Spectral Investigations

Autor:	Olena Litsis, Vladimir Ovchynnikov, Tatiana Sliva, Svitlana Shishkina, Vladimir Amirkhanov
Jazyk:	angličtina
Rok vydání:	2018
Předmět:	lanthanide carbacylamidophosphate phosphoryl ligand six-coordinate lanthanide complex Chemistry QD1-999 General. Including alchemy QD1-65
Zdroj:	Chemistry Journal of Moldova: General, Industrial and Ecological Chemistry, Vol 13, Iss 1, Pp 15-23 (2018)
Druh dokumentu:	article
ISSN:	1857-1727 2345-1688
DOI:	10.19261/cjm.2017.466
Popis:	New mononuclear six-coordinate lanthanide coordination compounds [Ln (HL)3Cl3] (HL = (2,2,2-trichloro-N-(dipiperidin-1-yl-phosphoryl)acetamideCCl3C(O)N(H)P(O)[N(CH2)5]2, carbacylamidophosphate (CAPh) type ligand) have been synthesized from non-aqueous solutions. The complexes have been characterized by elemental analysis, spectroscopic methods (FTIR, 1H- and 31P-NMR, UV-Vis). The structure of [Sm(HL)3Cl3] has been further confirmed by single crystal X-ray diffraction analysis.
Databáze:	Directory of Open Access Journals
Externí odkaz:	https://doaj.org/article/064a956fbd744c51a6356927b3724e7c Zobrazit plný text záznamu View record in DOAJ