Structural characterization of a new samarium–sodium heterometallic coordination polymer
Autor: | Ashley M. Hastings, Ashley Williams, Robert G. Surbella III, Amy E. Hixon, Ana Arteaga |
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Jazyk: | angličtina |
Rok vydání: | 2024 |
Předmět: | |
Zdroj: | Acta Crystallographica Section E: Crystallographic Communications, Vol 80, Iss 3, Pp 267-270 (2024) |
Druh dokumentu: | article |
ISSN: | 2056-9890 20569890 |
DOI: | 10.1107/S2056989024001051 |
Popis: | Lanthanide-containing materials are of interest in the field of crystal engineering because of their unique properties and distinct structure types. In this context, a new samarium–sodium heterometallic coordination polymer, poly[tetrakis(μ2-2-formyl-6-methoxyphenolato)samarium(III)sodium(I)], {[SmNa(C8H7O3)4]·solvent}n (Sm-1), was synthesized and crystallized via slow evaporation from a mixture of ethanol and acetonitrile. The compound features alternating SmIII and NaI ions, which are linked by ortho-vanillin (o-vanillin) ligands to form a mono-periodic chain-like coordination polymer. The chains propagate along the [001] direction. Residual electron density of disordered solvent molecules in the void space could not be reasonably modeled, thus the SQUEEZE function was applied. The structural, vibrational, and optical properties are reported. |
Databáze: | Directory of Open Access Journals |
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