| Autor: |
Zhongrui Chen, Gabriel Canard, Olivier Grauby, Benjamin Mourot, Olivier Siri |
| Jazyk: |
angličtina |
| Rok vydání: |
2023 |
| Předmět: |
|
| Zdroj: |
Molecules, Vol 28, Iss 24, p 8113 (2023) |
| Druh dokumentu: |
article |
| ISSN: |
1420-3049 |
| DOI: |
10.3390/molecules28248113 |
| Popis: |
Tetraamino-tetranitro-azacalixarene 5 is at the crossroad of two different families of compounds depending on the conditions and the agent used to reduce the NO2 groups: (1) azacalixphyrin 7 in neutral medium, or (2) phenazinium of type 8 in acidic medium. The key role of the N-substituted amino functions at the periphery is highlighted by investigating octaaminoazacalixarene as a model compound, and by using the corresponding tetrahydroxy-tetranitro-azacalixarene 15 as a precursor, which behaves differently. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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