| Autor: |
Valter Nunes Trindade-Junior, Marcos Corazza, Edson Antonio Da Silva, Reginaldo Guirardello |
| Jazyk: |
angličtina |
| Rok vydání: |
2019 |
| Předmět: |
|
| Zdroj: |
Chemical Engineering Transactions, Vol 74 (2019) |
| Druh dokumentu: |
article |
| ISSN: |
2283-9216 |
| DOI: |
10.3303/CET1974201 |
| Popis: |
Gamma-valerolactone (GVL) is used in green technology to produce chemicals and biofuels. Separation of GVL from mixtures within a process is a recurring challenge in chemical plants. Experimental boiling point determination containing its mixtures is fundamental as a preliminary stage of vapor-liquid equilibrium studies. The boiling point of binary mixtures of GVL/water and GVL/ethanol were measured at five compositions each, and range pressure from about 7.0 ?????? to 91.0 ?????? (±0.8??????). Experiments were carried out to determine the boiling point using a simplified ebulliometer. The experimental data were correlated with the Non-Random Two Liquid (NRTL) model. The correlated parameters of the NRTL model were used to calculate the vapor-liquid equilibrium of the mixture using the methodology of Gibbs energy minimization with ideal vapor phase. Key Words: Gamma-valerolactone, Boiling point, NRTL. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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