Diaquabis[5-(2-pyridyl)tetrazolato-κ2N1,N5]iron(II)

Autor: Min Hu, Song-Tao Ma, Liang-Qi Guo, Shao-Ming Fang
Jazyk: angličtina
Rok vydání: 2009
Předmět:
Zdroj: Acta Crystallographica Section E, Vol 65, Iss 4, Pp m382-m382 (2009)
Druh dokumentu: article
ISSN: 16005368
1600-5368
DOI: 10.1107/S1600536809007892
Popis: The title complex, [Fe(C6H4N5)2(H2O)2], was synthesized by the reaction of ferrous sulfate with 5-(2-pyridyl)-2H-tetrazole (HL). The FeII atom, located on a crystallographic center of inversion, is coordinated by four N-atom donors from two planar trans-related deprotonated L ligands and two O atoms from two axial water molecules in a distorted octahedral geometry. The FeII mononuclear units are further connected by intermolecular O—H...N and C—H...O hydrogen-bonding interactions, forming a three-dimensional framework.
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