The Two-Stage Air–CO Activation in the Preparation of Activated Carbons. I. Characterization by Gas Adsorption

Autor: F. Rodríguez-Reinoso, A. Linares-Solano, M. Molina-Sabio, J. de D. López-González
Jazyk: angličtina
Rok vydání: 1984
Předmět:
Zdroj: Adsorption Science & Technology, Vol 1 (1984)
Druh dokumentu: article
ISSN: 0263-6174
2048-4038
02636174
DOI: 10.1177/026361748400100304
Popis: Three different methods for the preparation of activated carbons from almond shells and olive stones have been carried out in the temperature range 1073–1123 K: (a) carbonization in N 2 followed by activation in CO 2 ; (b) direct activation in CO 2 and (c) treatment of the raw material in air at 573 K followed by activation in CO 2 . The characterization of the samples by gas adsorption and mercury porosimetry has shown that methods (a) and (b) yield similar results (and consequently it is preferable to use the direct activation) and that method (c) gives the best results, both in an adsorptive capacity and in the overall yield. On the other hand, the carbons from almond shells are more micro- and mesoporous whereas those from olive stones are more macroporous; in any case, the adsorptive capacity for gas adsorption of activated carbons prepared from both raw materials is very large.
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