| Autor: |
Zhi-Yuan Chen, Zi-Lu Wang, Jin-Bo Zhao, Yun-He Xu |
| Jazyk: |
angličtina |
| Rok vydání: |
2024 |
| Předmět: |
|
| Zdroj: |
Tetrahedron Chem, Vol 12, Iss , Pp 100093- (2024) |
| Druh dokumentu: |
article |
| ISSN: |
2666-951X |
| DOI: |
10.1016/j.tchem.2024.100093 |
| Popis: |
A palladium/TADDOL-derived phosphonate catalyzed desymmetric ring-opening coupling bewteen prochiral silacyclobutanes and alkyl terminal alkynes was developed. This catalytic system facilitates the formation of optically active allyl vinylsilane compounds featuring a quaternary silicon-stereogenic center, achieving good to high yields and moderate to good enantiomeric ratios. This approach significantly broaden the scope of ring-opening desymmetrization reactions involving silacyclobutanes under transition metal catalysis. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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