| Autor: |
PETER STEEL, MARIJA BARANAC, MILOVAN STOJANOVIC, ZDRAVKO DZAMBASKI, RADE MARKOVIC |
| Jazyk: |
angličtina |
| Rok vydání: |
2003 |
| Předmět: |
|
| Zdroj: |
Journal of the Serbian Chemical Society, Vol 68, Iss 4-5, Pp 383-390 (2003) |
| Druh dokumentu: |
article |
| ISSN: |
0352-5139 |
| Popis: |
A study on the regiospecificity of the base-catalyzed reaction of activated b-oxonitriles 1 with diethyl mercaptosuccinate affording the title compounds 3 is reported. Other competitive heterocyclic products, that is 4-oxo-1,3-thiazinanes 4, derivatives of tetrahydrothiophene 5 and/or thiacyclohexane 6 which on the grounds of mechanistic considerations could be formed, were not observed. Spectroscopic and experimental evidence, together with theoretical considerations, provides a reasonable explanation for the observed regiospecificity. |
| Databáze: |
Directory of Open Access Journals |
| Externí odkaz: |
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