Methane Assisted Chemical Looping Water Splitting Performance of Sr2FeMo0.6Ni0.4O6-δ Double Perovskite for Solar Fuels Production

Autor: Andrea Strazzolini, Francesco Orsini, Salvatore Francesco Cannone, Domenico Ferrero, Marta Boaro, Jordi Llorca, Georgios Dimitrakopoulos, Alessandro Trovarelli, Massimo Santarelli, Ahmed Ghoniem
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: SolarPACES Conference Proceedings, Vol 2 (2024)
Druh dokumentu: article
ISSN: 2751-9899
DOI: 10.52825/solarpaces.v2i.907
Popis: In this work, we performed a preliminary investigation on the redox behaviour of Sr2FeMo0.6Ni0.4O6-δ (SFMN) double perovskite in H2-H2O and CH4-H2O redox cycles in order to explore the potential use of this oxide as an Oxygen Carrier (OC) in fuel-assisted Chemical Looping Water Splitting (CLWS) processes driven by concentrated solar energy. The results were compared with our previous findings on the Reverse Water Gas Shift Chemical Looping (RWGS-CL) reaction. The improvement in performance due to the bimetallic exsolution on the OC surface is observed. This OC exhibits interesting activity and stability over CH4-assisted CLWS cycling. Future investigations are planned to examine the structural transformations that might impact the redox behaviour of this material in water splitting processes.
Databáze: Directory of Open Access Journals