Bis{(S)-(−)-N-[(2-biphenyl)methylidene]-1-(4-methoxyphenyl)ethylamine-κN}dichloridopalladium(II)

Autor: Bertin Anzaldo, René Gutiérrez Pérez, Guadalupe Hernández Téllez, Ángel Mendoza, Gloria E. Moreno Morales
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: IUCrData, Vol 9, Iss 7, p x240555 (2024)
Druh dokumentu: article
ISSN: 2414-3146
24143146
DOI: 10.1107/S2414314624005558
Popis: The PdII complex bis{(S)-(−)-N-[(biphenyl-2-yl)methylidene]1-(4-methoxyphenyl)ethanamine-κN}dichloridopalladium(II), [PdCl2(C22H21NO)2], crystallizes in the monoclinic Sohncke space group P21 with a single molecule in the asymmetric unit. The coordination environment around the palladium is slightly distorted square planar. The N—Pd—Cl bond angles are 91.85 (19), 88.10 (17), 89.96 (18), and 90.0 (2)°, while the Pd—Cl and Pd—N bond lengths are 2.310 (2) and 2.315 (2) Å and 2.015 (2) and 2.022 (6) Å, respectively. The crystal structure features intermolecular N—H...Cl and intramolecular C—H...Pd interactions, which lead to the formation of a supramolecular framework structure.
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