Clean recycling of spent nickel-based single-crystal superalloy by molten magnesium

Autor: Hao Li, Junjie Wang, Feng Liu, Xueyi Guo, Zean Wang, Dawei Yu, Qinghua Tian
Jazyk: angličtina
Rok vydání: 2024
Předmět:
Zdroj: Journal of Materials Research and Technology, Vol 30, Iss , Pp 3960-3966 (2024)
Druh dokumentu: article
ISSN: 2238-7854
DOI: 10.1016/j.jmrt.2024.04.145
Popis: Nickel-based single-crystal superalloys are designed for extreme conditions due to their superior corrosion and creep resistance properties. However, these pose challenges in the subsequent recycling after reaching their end-of-life. Molten magnesium (Mg) can rapidly corrode the stable spent nickel-based superalloys and selectively dissolve nickel (Ni). This waste-free process represents an effective method for recycling spent superalloys and accomplishing metal regeneration. This study investigates the mechanism of selectively dissolving Ni from DD5, a nickel-based single-crystal superalloy, by optimizing process temperature, time, and Mg content in an inert atmosphere. Vacuum distillation was employed to separate the resulting Mg, residual superalloy (i.e., the material left post-extraction), and Ni-rich alloy (i.e., the metal product selectively extracted). The findings revealed that the residual superalloy after selective Ni dissolution is characterized by a porous skeleton structure with pore sizes predominantly ranging from 2 to 30 nm and a low compressive strength which is 1/10 of the original DD5 superalloy.
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