The preparation and characterization of uns-cis-(ethylene-diamine-N,N'-di-3-propionato)(N-alkylethylenediamines)cobalt(III) complexes

Autor:	Sabo Tibor J., Grgurić Sanja R.
Jazyk:	angličtina
Rok vydání:	2000
Předmět:	cobalt(iii) complexes ethylenediamine-n n'-di-3-propionic acid n-alkylethylenediamines Chemistry QD1-999
Zdroj:	Journal of the Serbian Chemical Society, Vol 65, Iss 3, Pp 167-171 (2000)
Druh dokumentu:	article
ISSN:	0352-5139 1820-7421
DOI:	10.2298/JSC0003167S
Popis:	Three octahedral cobalt(III) complexes of the general formula uns-cis-[Co(eddp)(R- en)]Cl.2H2O, where eddp = the tetradentate ONNO-type ligand ethylenediamine-N,N'-di-3-propionate and R-en = a bidentate NN-type ligand, either N-methyl, N-ethyl or N-isopropylethylenediamine. The complexes were prepared by the reaction of sodium uns-cis- (ethylenediamine-N,N'-di-3-propionato)(carbonato)cobaltate(III)dihydrate with the corresponding diamine. They were isolated chromatographically and characterized by elemental analysis, infrared and electronic absorption spectroscopy.
Databáze:	Directory of Open Access Journals
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