{S-Benzyl 3-[(6-methylpyridin-2-yl)methylidene]dithiocarbazato}nickel(II) monohydrate
| Autor: | Karen A. Crouse, Thahira B. S. A. Ravoof, Mohamed Ibrahim Mohamed Tahir, Siti Aminah Omar |
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| Jazyk: | angličtina |
| Rok vydání: | 2012 |
| Předmět: | |
| Zdroj: | Acta Crystallographica Section E, Vol 68, Iss 3, Pp m316-m317 (2012) |
| Druh dokumentu: | article |
| ISSN: | 16005368 1600-5368 |
| DOI: | 10.1107/S1600536812006952 |
| Popis: | The structure of the title compound, [Ni(C15H14N3S2)2]·H2O, has one molecule in the asymmetric unit, along with a solvent water molecule. The two different Schiff base moieties coordinate to the central NiII ion as tridentate N,N′,S-chelating ligands, creating a six-coordinate distorted octahedral environment [the smallest angle being 77.43 (7)° and the widest angle being 169.99 (7)°]. The mean planes of the two ligands are nearly orthogonal to each other with an angle of 89.53 (6)°. The packing of the complex is supported by O—H...N and O—H...S hydrogen bonding between the solvent water molecule and the uncoordinated N and S atoms of neighbouring ligands. |
| Databáze: | Directory of Open Access Journals |
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