Autor: |
Saikat Mukherjee, Mario Barbatti |
Jazyk: |
angličtina |
Rok vydání: |
2022 |
Předmět: |
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Zdroj: |
Results in Chemistry, Vol 4, Iss , Pp 100521- (2022) |
Druh dokumentu: |
article |
ISSN: |
2211-7156 |
DOI: |
10.1016/j.rechem.2022.100521 |
Popis: |
Ultrafast (sub-picosecond) internal conversion can occur between electronic states without energetically accessible conical intersections. For that, the molecule must remain in a region of at least weak nonadiabatic coupling, multiplying the odds of a transition, each with a small probability. This phenomenon is discussed with a simple analytical model correlating the instantaneous probability to the lifetime. |
Databáze: |
Directory of Open Access Journals |
Externí odkaz: |
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